It's good that you're creating a custom ADM, but did you look to disable password caching in the GPO: User Configuration->Windows Settings->Internet Explorer Maintenance->Advanced
In order to see the Advanced folder you need to set Internet Explorer Maintenance to "preference mode". Do that by highlighting Internet Explorer Maintenance, then click Action->preference mode. I made a GPO this way that deletes a users temp internet files everytime they close the browser.
You may find what you need in there.
Tony


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