If all you did was upgrade your DC's from 2003 to 2008 (or 2008R2), there shouldn't be a difference in how an XP client is processing Group Policy. Specifically how are you removing accounts from the local Administrators? There are multiple ways to do it: scripts, GP Preferences, etc. The first thing I always do when something doesn't run correctly is to check the Event Log to see if there are errors. It is possible that the policy has a problem. What happens if you run a gpupdate /force, does the policy run then? Has this policy been changed recently? Did you check that all of your DC's (including sysvol) are replicating after the upgrade?


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