Since you have changed the policy, and it only works half the time, it is possible you have an FRS member in journal wrap. When the old address sticks, is that machine properly applying the policy? If you get the old address and the new address randomly, it is quite possible you have a journal wrap. Basically, one or more machines in journal wrap keep their version of the policies in SYSVOL, and never replicate in changes that have been made.
As far as tattooing, you can probably find a method to push the following key.
HKEY_CURRENT_USER\Software\Microsoft\Internet Explorer\Main
On the right hand side is a value called "StartPage"


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