You will have to get rid of the policy with the 'Restricted Groups' as it will override anything else. Then from a Vista or better computer, create a new policy. Go to 'Computer Config\Preferences\Control Panel Settings\Local Users and Groups'. Add a new Group and select the Administrators built in group. Set this one up with your default membership. I don't think you need to add the default Admin groups like you do with Restricted Groups, (but be sure to test!).
Now add another entry for the same administrators group, add the single user account you want to add for a specific computer, then go to the 'Common' tab and check the 'Item Level Targeting' box. Under 'New Item' select 'Computer Name' and add the name of the computer you want. This will imit that specific policy entry to only that computer. You can then add any more entries you need the same way.
I believe these entries are additive, so they should overlap - the one entry will add your management accounts and the others will add the machine specific accounts needed. But obviously test thouroughly since I have never actually used a GPO in this specific scenario.
Hope this helps,
Scott


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