The thing with profiles where you have username and username.domain is usually because either:
they have a local account and domain account with same name (you should not need local accounts at all, just use cached credentials)
you changed the domain and rejoined the machines to new domain, but there was already a profile in their username so it created a new one.
It sounds like the machine is giving them a logon while the network is still starting. Try turning off XP's fast boot:
Computer/Admin Templates/System/Logon
configure 'Always wait for the network at computer startup and logon'
Also try setting the network card to a fixed speed instead of auto - this saves time on auto-negotiation with the switch and gets connected faster.


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